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PRODUCT
CODE: |
705.00.0000.x |
SPECIFICATION
CODE: |
QASI018 |
DATE: |
28.04.2004 |
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1.
Product Identification |
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Product name: |
BODY HARDENER FOR BODY POLYESTER PUTTIES |
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Product type: |
PEROXIDE |
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2.
Chemical |
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Chemical name |
Dibenzoyl peroxide paste with diisobutyl phthalate |
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Form: |
Paste |
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Color: |
Red. |
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Hazardous
ingredients: Name
CAS-Nr.
Conc.
Symbol
R-Phrases Dibenzoyl
peroxide.
000094-36-0
30-60% E, Xi
R2-36-43-7 Diisobutyl
phthalate
000084-69-5
15-27% |
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3.
Hazards Identification |
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May cause fire Irritating to eyes May cause sensitization by skin contact. |
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4.
First - Aid Measures |
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Symptoms
and effects:
No
typical symptoms and effects known. |
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General: |
In all cases of doubt, or when symptoms persist, seek medical
attention. |
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Inhalation: |
Move to fresh air, rest half upright position, loosen clothing. Seek
medical advice after significant exposure. |
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Skin: |
Wash with plenty of soap and water immediately. Take all contaminated
clothes off immediately. In case of skin eruption seek medical advice. |
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Eyes: |
Rinse immediately with plenty of water. Eyelids should be help away
from the eyeball to ensure thorough rinsing. Seek medical advice if
irritation develops. |
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Ingestion: |
Do not induce vomiting because
of risk of aspiration. Seek medical advice. |
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5.
Fire-Fighting Measures |
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Extinguishing
measures |
Extinguish a small fire with powder or carbon dioxide then apply water
to prevent re-ignition. |
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Suitable: |
Powder, carbon dioxide, foam, watermist (large amounts only). |
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Not to be used: |
Halones. |
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Hazardous
thermal decomposition and combustion products |
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Carbon dioxide, Benzoic acid, Benzene, Diphenyl, Phenylbenzoate. |
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Protective
equipment |
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Wear protective clothing and use self- contained breathing apparatus.
In case of fire and/or explosion do not breathe fumes. |
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6.
Accidental Release Measures |
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Personal
precautions: |
Put on adequate protective equipment. |
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Environment
precautions: |
Collect as much as possible in a clean container for (preferable)
reuse or disposal. Do not empty into drains. |
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Cleaning
procedures: |
Sweep up with dustpan and brush off inert material, flushing the
remainder with water. Absorb the remainder with e.g. vermiculite. |
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7.
Handling and Storage |
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Handling: |
Never weight out in the storage room. Keep product away from heat and
sources of ignition. No sparking tools should be used. Never bring
peroxide into direct contact with accelerator during processing. Weight
out and add peroxide and accelerator separately. |
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Storage: |
Keep in cool, well-ventilated place. Keep away from reducing agents
(e. g. amines), acids, alkalis an heavy metal compounds. Store in
accordance with local / national regulations. |
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8.
Exposure Controls / Personal Protection |
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Respiratory
protection: |
The usual precautionary measures for handling chemicals should be
observed. Provide adequate ventilation. |
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Hand
protection: Eye
protection: Skin
protection: |
Protective gloves. Safety goggles. Protective clothing. |
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9.
Physical and Chemical Properties |
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-Appearance |
Smooth unctuous paste |
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-Autoignition |
>380°C
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-Boiling
point |
Do not distil. |
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-Flash
point |
Above the SADT value |
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-Density: |
1.14-1.17 g/cm3 |
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-Melting
range |
-10°C |
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-Odour |
Characteristic (faint) |
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-Partition
coefficient |
Not known |
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-pH |
weak acid |
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-Solubility
in water |
Not soluble. |
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-Vapour
density |
Not known |
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-Vapour
pressure |
not determined |
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-Viscosity |
thixotropic paste |
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10.
Stability and Reactivity |
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Conditions
to avoid: |
Violent reactions may be expected with acid, alkali, heavy metals and
reducing agents. Avoid contact with incompatible substances and rust. Do
not mix with peroxide accelerators. Do not mix with reducing agents. |
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Materials
to avoid: |
Use only Stainless steel 316, PVC, PE, ore glass-lined equipment. |
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Hazardous
decomposition products: |
Carbon dioxide, Benzoic acid, Benzene, Diphenyl, Phenylbenzoate. |
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11.
Toxicological Information |
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Acute
toxicity: |
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Oral: |
rat:>5000
mg/Kg |
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Inhalation
LC50: |
rat:>24.3
mg/l; 4 hours exposure time max. attainable concentration. |
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Inhalation: |
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Skin: |
Non-irritating (4 hours exposure time) |
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Eyes: |
Mildly irritating (5 min exposure time) |
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Ingestion: |
Slightly toxic. Ingestion of moderate quantities may cause abdominal
discomfort, nausea and drowsiness. |
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12.
Ecological Information |
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Ecotoxity:
fish Acute
toxicity, 96h-LC50 = 2.0 mg/l
bacteria Activated
sludge respiration inhibition test EC50 = 35 mg/l
Degradation
Biotic:
Readily
biodegradable (Closed bottle test).
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13.
Disposal Considerations |
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Methods
of disposal: |
Controlled incineration but according to local regulations. Sweep up with dustpan and brush off inert material, flushing the
remainder with water. Absorb the remainder with e.g. vermiculite. |
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Danger(s): |
Dilute before burning with organic solvents. Controlled incineration
according to local regulations is always preferred. If not possible burn
in small portions on a remote place, using a torch with a long rod to
ignite the material. |
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14.
Transport Information |
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Special
precautions: |
Not applicable |
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Classification |
O, Xi |
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UN no. |
3108 |
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Packaging group |
II |
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ADR/RID |
5.2 |
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ICAO/IATA |
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IMDG-code |
3108 |
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Stow away from foodstuffs |
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Marine pollutant |
NO |
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Shipping name |
ORGANIC PEROXIDE TYPE E, SOLID; (DIBENZOYL PEROXIDE). |
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15.
Regulatory Information |
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EEC
classification |
Reference: 91/155/EEC |
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Contains: |
Organic peroxide type e, solid |
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Symbol: |
O,
Oxidant Xi
Irritant |
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Risk-phrases: |
R7
May cause fire. R36
Irritation to eyes. R43
May cause sensitization by skin contact. |
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S3/7
Keep container tightly closed in a well-ventilated place. S14
Keep away from reducing agents e.g. amines, acids, alkalies, heavy
metal compounds
(e.g. accelerators, driers, metal soaps). S26
In case of contact with skin, rinse immediately with plenty of
water and seek medical
Advice. S28
After contact with skin, wash immediately with plenty of soap and
water. S50
Do not mix with peroxide accelerators. S50
Do not mix with reducing agents. |
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16.
Other Information |
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Replaces
MSDS dated: |
30.11.2002 |
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Product Data Management HB BODY S.A. 570 22 SINDOS IND. AREA – THESSALONIKI – GREECE TEL. 2310.790.000 FAX 2310.790.010 The data given here is based on current knowledge. The purpose of this
Safety Data Sheet is to describe the products in terms of their safety
requirements. The data does not imply any warranty with regard to product
properties. |
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